Preheat the oven to 180°C (356°F) and grease and line two 8-inch round cake pans.
In a large bowl, mix together the flour, cocoa powder, salt, baking powder, and baking soda. Set it aside.
In a separate bowl, whisk together the sourdough starter, eggs, vanilla, oil, milk, and sugars.
Pour the wet mixture into the flour mixture and fold gently for a minute before pouring over the hot coffee.
Mix briskly together but don't over mix.
Pour into the prepared cake pans and bake for 25-30 minutes until a skewer inserted into the cakes comes out clean.